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A buffer solution contains carbonic acid (H2CO3) and sodium bicarbonate (NaHCO3) , each at a concentration of 0.100 M.The relevant equilibrium is shown below.What is the pH of this buffer solution? H2CO3(aq) + H2O(l) A buffer solution contains carbonic acid (H<sub>2</sub>CO<sub>3</sub>)  and sodium bicarbonate (NaHCO<sub>3</sub>) , each at a concentration of 0.100 M.The relevant equilibrium is shown below.What is the pH of this buffer solution? H<sub>2</sub>CO<sub>3</sub>(aq)  + H<sub>2</sub>O(l)    H<sub>3</sub>O<sup>+</sup>(aq)  + HCO<sub>3</sub>−(aq)  K<sub>a</sub> = 4.5 × 10<sup>−7</sup> A) 4.50 B) 7.00 C) 6.35 D) 7.65 E) 2.16 H3O+(aq) + HCO3−(aq) Ka = 4.5 × 10−7


A) 4.50
B) 7.00
C) 6.35
D) 7.65
E) 2.16

F) B) and D)
G) A) and B)

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A solution containing a buffer has an initial pH of 8.78.If a student adds 5 drops of HCl(aq) to this solution, what would be a reasonable pH for the resulting solution?


A) 5.22
B) 7.00
C) 8.64
D) 8.78
E) 8.89

F) All of the above
G) B) and D)

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What is the pH of a 1.0 × 10−4 M solution of KOH?


A) 4.00
B) 6.00
C) 7.00
D) 10.00
E) 14.00

F) B) and D)
G) All of the above

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Which of the following best represents the autoionization, or self-ionization, of water?


A) H2O(l) → H+(aq) + OH-(aq)
B) 2H2O(l) Which of the following best represents the autoionization, or self-ionization, of water? A) H<sub>2</sub>O(l)  → H+(aq)  + OH-(aq)  B) 2H<sub>2</sub>O(l)    2H<sub>2</sub>(aq)  + O<sub>2</sub>(aq)  C) 2H<sub>2</sub>O(l)    H3O+(aq)  + OH-(aq)  D) H<sub>2</sub>O(l)  → H<sub>2</sub>(aq)  + O<sub>2</sub><sup>-</sup>(aq)  E) H+(aq)  + OH-(aq)  → H<sub>2</sub>O(l) 2H2(aq) + O2(aq)
C) 2H2O(l) Which of the following best represents the autoionization, or self-ionization, of water? A) H<sub>2</sub>O(l)  → H+(aq)  + OH-(aq)  B) 2H<sub>2</sub>O(l)    2H<sub>2</sub>(aq)  + O<sub>2</sub>(aq)  C) 2H<sub>2</sub>O(l)    H3O+(aq)  + OH-(aq)  D) H<sub>2</sub>O(l)  → H<sub>2</sub>(aq)  + O<sub>2</sub><sup>-</sup>(aq)  E) H+(aq)  + OH-(aq)  → H<sub>2</sub>O(l) H3O+(aq) + OH-(aq)
D) H2O(l) → H2(aq) + O2-(aq)
E) H+(aq) + OH-(aq) → H2O(l)

F) B) and E)
G) C) and E)

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What is the hydronium ion concentration of pure water at 25°C?


A) 7.0 × 107 M
B) 7.0 × 10-7 M
C) 1.0 × 107 M
D) 1.0 × 10-7 M
E) 1.0 × 10-14 M

F) A) and C)
G) All of the above

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Which of the following is an example of a diprotic acid?


A) NH2
B) H2SO4
C) HCl
D) CH4
E) NH2 and H2SO4 are correct.

F) A) and D)
G) A) and C)

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A particular buffer solution consists of a weak acid and its conjugate base.How could this buffer solution be modified so as to increase its buffer capacity against added base?


A) Increase the concentration of the weak acid.
B) Increase the concentration of its conjugate base.
C) Use a strong base and its conjugate acid instead.
D) Use a strong acid and its conjugate base instead.
E) Make the concentrations of the weak acid and its conjugate base equal.

F) A) and B)
G) A) and C)

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The combination of a weak acid and a strong acid form a buffer solution.

A) True
B) False

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The concentration of a weak acid or base affects its degree of dissociation in water.

A) True
B) False

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For the reaction shown below, which of the following correctly represents a conjugate acid-base pair? HCO2H(aq) + H2O(l) For the reaction shown below, which of the following correctly represents a conjugate acid-base pair? HCO<sub>2</sub>H(aq)  + H<sub>2</sub>O(l)    H<sub>3</sub>O<sup>+</sup>(aq)  + HCO<sub>2</sub>−(aq)  A) HCO<sub>2</sub>H/H<sub>3</sub>O<sup>+</sup> B) HCO<sub>2</sub>H/H<sub>2</sub>O C) H<sub>2</sub>O/HCO<sub>2</sub>- D) H<sub>3</sub>O<sup>+</sup>/HCO<sub>2</sub>- E) HCO<sub>2</sub>H/HCO<sub>2</sub>− H3O+(aq) + HCO2−(aq)


A) HCO2H/H3O+
B) HCO2H/H2O
C) H2O/HCO2-
D) H3O+/HCO2-
E) HCO2H/HCO2

F) C) and D)
G) B) and E)

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Calculate the molar concentration of a sodium hydroxide solution if 60.00 mL of this solution were required to neutralize 30.00 mL of a 0.150 M hydrochloric acid solution.NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)


A) 3.00 M
B) 6.00 M
C) 0.0750 M
D) 0.150 M
E) 2.25 M

F) C) and D)
G) B) and E)

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According to Arrhenius' theory of acids and bases, acids increase the hydrogen ion concentration in water.

A) True
B) False

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If the hydronium ion concentration of an aqueous solution at 25°C is 5 × 10-6 M, what is the hydroxide ion concentration?


A) 2 × 10-10 M
B) 2 × 10-9 M
C) 2 × 10-8 M
D) 2 × 107 M
E) 2 × 1019 M

F) A) and B)
G) None of the above

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What is the pH of a 0.035 M HCl solution?


A) 3.50
B) 1.46
C) 2.27
D) 5.59
E) 12.54

F) D) and E)
G) B) and D)

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Consider the following generalized buffer solution equilibrium: BH+(aq) + H2O(l) Consider the following generalized buffer solution equilibrium: BH<sup>+</sup>(aq)  + H<sub>2</sub>O(l)    H<sub>3</sub>O<sup>+</sup>(aq)  + B(aq)  When a small amount of a strong base such as sodium hydroxide is added to the solution, which of the four species shown would experience an increase in concentration? (Hint: Use LeChatelier's principle.)  A) BH<sup>+</sup> B) H<sub>2</sub>O C) H<sub>3</sub>O<sup>+</sup> D) B E) None of the species would increase in concentration. H3O+(aq) + B(aq) When a small amount of a strong base such as sodium hydroxide is added to the solution, which of the four species shown would experience an increase in concentration? (Hint: Use LeChatelier's principle.)


A) BH+
B) H2O
C) H3O+
D) B
E) None of the species would increase in concentration.

F) All of the above
G) None of the above

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Which of the following correctly describes what is meant by the term neutralization?


A) the reaction between hydroxide (OH−) and water to form a base
B) the reaction between a proton (H+) and water to form a hydronium ion (H3O+)
C) the reaction between an acid and a base to form a salt and water
D) the reaction between two molecules of water, one acting as an acid and the other acting as a base
E) the reaction between an oxidizing agent and a reducing agent

F) All of the above
G) A) and B)

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A sample of black coffee was measured to have [H3O+] = 7.94 × 10−6.What is TRUE about this solution?


A) The solution is acidic.
B) The solution contains less hydronium ions than pure water itself.
C) The solution does not contain any OHions.
D) The solution has [OH] = 7.94 × 10−6.
E) The pH of the solution is 7.94.

F) A) and D)
G) C) and D)

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What is always a characteristic of a solution that contains a buffer?


A) The solution is neutral and has a pH of 7.
B) The solution contains a small amount of solute dissolved in a large volume of solvent.
C) The solution has been diluted by the addition of solvent.
D) The solution resists large changes in pH when small amounts of acids or bases are added.
E) The solution maintains a constant pH value; no amount of added acid or base can change the pH.

F) All of the above
G) A) and B)

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A buffer solution contains acetic acid (HC2H3O2) at a concentration of 0.225 M and sodium acetate (NaC2H3O2) at a concentration of 0.164 M.The value of Ka for acetic acid is 1.75 × 10-5.What is the pH of this buffer solution?


A) 0.137
B) 0.862
C) 2.40
D) 4.62
E) 4.76

F) A) and E)
G) A) and B)

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