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Generally speaking, both anions and cations have larger radii than their parent atoms.

A) True
B) False

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A correct description for the electron configuration of an iron atom is


A) [Ar] 3s2 3d6, paramagnetic.
B) [Ar] 4s2 3d6, diamagnetic.
C) [Ar] 4s1 3d7, paramagnetic.
D) [Ar] 3d8, paramagnetic.
E) [Ar] 4s2 3d6, paramagnetic.

F) A) and B)
G) C) and D)

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The number of orbitals in a d subshell is ________.

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Calculate the frequency of visible light having a wavelength of 589.3 nm.


A) 176.7 s-1
B) 1.966 × 10-15 s-1
C) 1.391 × 10-11 s-1
D) 5.091 × 1014 s-1
E) 5.660 × 103 s-1

F) A) and B)
G) D) and E)

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Which one of the following types of radiation has the lowest frequency?


A) radio waves
B) infrared radiation
C) microwave radiation
D) X-rays
E) ultraviolet rays

F) C) and D)
G) B) and C)

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Which of the following gives a possible quantum number assignment for the last electron added to the sodium atom when developing the electron configuration using the aufbau principle? Which of the following gives a possible quantum number assignment for the last electron added to the sodium atom when developing the electron configuration using the aufbau principle?

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Which atom has the largest first ionization energy?


A) Al
B) Sr
C) Ga
D) Cr
E) Fr

F) A) and B)
G) A) and D)

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What is the wavelength of radiation which has an energy of 216.1 kJ per mole of photons?


A) 655.9 nm
B) 546.1 nm
C) 108.8 nm
D) 589.3 nm
E) 977.7 nm

F) D) and E)
G) A) and C)

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The notation for the subshell with n = 4 and l = 2 is


A) 4d subshell.
B) 4p subshell.
C) 4f subshell.
D) 4s subshell.
E) There is no subshell fitting this description.

F) A) and E)
G) B) and E)

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An electron with an n = 2 quantum number may also have a quantum number l = 2.

A) True
B) False

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For every value of n, there is an s subshell.

A) True
B) False

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The frequency of a wave is related to the energy of the radiation.

A) True
B) False

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In the Rydberg equation, if n1 = 1, an acceptable value of n2 is ________.

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Which placement of electrons is never encountered in the ground state configuration of an atom?


A) 3d4 with 4 unpaired electrons
B) 3d7 with 7 unpaired electrons
C) 3p1 with 1 unpaired electron
D) 3d9 with 1 unpaired electron
E) 4f 7 with 7 unpaired electrons

F) All of the above
G) A) and B)

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An electron behaves as if it were spread out in space around the nucleus in a sort of ________.

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The definite energies associated with specific wavelengths in the emission spectrum of atomic hydrogen suggest that


A) electrons have a smaller rest mass than photons.
B) photons have a smaller rest mass than electrons.
C) energy states of the electron in the hydrogen atom are quantized.
D) atomic hydrogen is more stable and has a lower potential energy than molecular hydrogen.
E) the potential energy of electrons in the atom can have any arbitrary value over a period of time, but the kinetic energy may only have certain specific values.

F) B) and E)
G) A) and C)

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The maximum number of electrons in an atom that can have the following exact same set of quantum numbers is ________. The maximum number of electrons in an atom that can have the following exact same set of quantum numbers is ________.

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Calculate the wavelength of the transition from n = 2 to n = 3 for an ion with a single electron, where the charge on the ion is +2.Hint: Use the Rydberg equation when calculating transition wavelength.

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The number of orbitals in a subshell with l = 3 is ________.

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Which radiation has the longest wavelength?


A) infrared radiation
B) radio waves
C) microwave radiation
D) ultraviolet rays
E) X-rays

F) A) and D)
G) B) and E)

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